Title Chemical fractionation in Low-mass Cores Pi Y. Aikawa Time 358 hrs 1. Name of program and authors Name: Chemical fractionation in Low-mass Cores Authors: Y. Aikawa, K. Tatematsu 2. One short paragraph with science goal(s) From recent observational studies, it became clear that the molecular abundances have local spatial variation within molecular cloud cores. In the central region of some prestellar cores C-bearing species (e.g. CO) are depleted, while molecular D/H ratio is significantly enhanced and depletion of N-bearing species are rare. Such fractionation is mainly caused by molecular depletion onto grains and subsequent gas-phase reactions. Detailed observation of the chemical fractionation reveals not only the gas-dust chemical interaction, but also helps us to understand the formation process of dense cores and their evolution, because spatial abundance variation is determined by a balance between physical and chemical timescales. Molecules to be observed are CO, N2H+, H2D+, etc. Our source list includes very young prestellar cores with little depletion, prestellar cores with significant depletion, and very young protostellar cores, which are not yet warm enough to start the hot-core type chemistry. We need imaging of the dust continuum emission for reference. We will observe two frequencies to disentangle the column density distribution and the dust temperature distribution. 3. Number of sources: 3 starless cores and 3 protostellar cores 4. Coordinates: 4.1. Rough RA and DEC 6 sources either in Lupus (RA=15, DEC=-40) or in Chamaeleon (RA=10:30, DEC=-78) or in Oph (RA=16:30, DEC=-24) or in Taurus (RA=04, DEC=+20)) 4.2. Moving target: no 4.3. Time critical: no 4.4. Scheduling constraints: (optional) 5. Spatial scales: 1. Angular resolution (arcsec): 2'' (For continuum, 5.we do not need 2" for comparison, but it would be better to observe 5.continuum at the same time slot, which means the same array 5.configuration. Otherwise, we must wait for array 5.re-configuration...) 5.2. Range of spatial scales/FOV (arcsec): 0.5'-2' Band 3: 2' - 9 field mosaic of FOV=50" Band 4: 2' - 25 field mosaic of FOV=33'' Band 6: 2' - 36 field mosaic of FOV=20'' Band 7: 0.5' - 5 field mosaic of FOV=17'' Band 9: 0.5' - 25 field mosaic of FOV=8'' 5.3. Required pointing accuracy: 0.1'' 6. Observational setup 6.1. Single dish total power data: required Observing modes for single dish total power: position switch 6.2. Stand-alone ACA: required 6.3. Cross-correlation of 7m ACA and 12m baseline-ALMA antennas: beneficial 6.4. Subarrays of 12m baseline-ALMA antennas: no 7. Frequencies: 7.1. Receiver band: Band 3, 4, 5, 6, 7, 8, or 9: 3, 4, 7, 9 (Band 6 for continuum ?) 7.2. Lines and Frequencies (GHz): Band 3 (3LO settings) (1) H13CO+ (1-0): 87GHz (2) N2H+ (1-0): 93GHz, C34S (2-1): 96GHz (3) C18O (1-0): 110GHz, C17O(1-0): 112GHz Band 4 (2LO settings): (1) DCO+ (2-1): 144GHz, DCN: 145GHz, C34S 2-1: 145GHz, CS(3-2): 147GHz (2) N2D+ (2-1): 154GHz Band 7 (1LO setting) (1) H2D+: 372GHz Band 9 (1LO setting) (1) HD2+: 692GHz 7.3. Spectral resolution (km/s): 0.2 km/s 7.4. Bandwidth or spectral coverage (km/s or GHz): 5km/s 8. Continuum flux density: 8.1. Typical value (Jy): 20-400 mJ/beam at B6, 0.5-10J/beam at B9 8.2. Required continuum rms (Jy or K): 4 mJ/beam at B6, 28mJ/beam at B9 8.3. Dynamic range within image: 100 8.4. Calibration requirements: absolute 10% repeatability 5% relative 5% 9. Line intensity: 9.1. Typical value (K or Jy): 0.5-5 K 9.2. Required rms per channel (K or Jy): 0.07 K 9.3. Spectral dynamic range: 7-70 9.4. Calibration requirements: absolute 10% repeatability 5% relative 5% 10. Polarization: no 10.1. Required Stokes parameters: 10.2. Total polarized flux density (Jy): 10.3. Required polarization rms and/or dynamic range: 10.4. Polarization fidelity: 10.5. Required calibration accuracy: 11. Integration time for each observing mode/receiver setting (hr): 6 sources x 9-field mosaic x 3 LO setting x 25 min =67.5 hrs (B3 line) 6 sources x 25-field mosaic x 2 LO setting x 15 min =75 hrs (B4 line) 3 sources x 5-field mosaic x 1LO setting x 120min =30 hrs (B7 line) 3 sources x 25-field mosaic x 1LOsetting x 120min=150 hrs (B9 line) 6 sources x 36-field mosaic x 1 min =3.6 hrs (B6 continuum) 6 sources x 320-field mosaic x 1 min = 32 hrs (B9 continuum) 12. Total integration time for program (hr): 358 hrs 13. Comments on observing strategy : (optional) We assume mosaic with 1-min imaging for continuum (The time will be reduced if OTF systhesis is available in 2012). OTF synthesis is preferable, because it will improve UV coverage drastically and it will save observing time largely.