Title:The 10 micron feature of Herbig Ae/Be candidates from the Pico dos Dias Survey Abstract: Herbig Ae/Be (HAeBe) objects are intermediate mass (2-10 M_sun) stars in the pre-main sequence. Some of their properties remain not well understood to date. Only a full multi-wavelength study is able to reveal the general properties of their circumstellar material. We propose a method of characterizing the circumstellar environment of such objects by a two-step strategy. First, the dust chemistry is constrained by a compositional fit of the silicate feature. Once the disk opacity is determined, the spectral energy distribution (SED) is then modeled with the flared disk model proposed by Dullemond et al. (2001). The preliminary results of the first step are shown in the present work. We have adopted the position unbiased sample of HAeBe candidates detected by the Pico dos Dias Survey (Vieira et al . 2003), to study the silicate feature from ISO observations. We have determined the dust grain fractions from fit of the 10 micron feature, with a combination of commonly adopted dust grain opacities. We have also studied its shape and correlation with the infrared spectral slope. We conclude that the amorphous carbon can be responsible for an important fraction of the dust grain composition, in spite of being neglected in previous similar studies (van Boekel et al. 2005; Bouwman et al. 2008). Besides, the studied 10 micron features follow an evolutionary sequence (from amorphous material absorption to crystalline grain emission), as previously reported by Kessler-Silacci et al. (2005). Our perspectives are to develop a SED automatic fitting tool, that uses the already derived dust opacities as an input. We also plan to extend our sample, in order to perform a statistical analysis of HAeBe disk properties.