Title:Tracing H2 density with CI and CO isotopologues Abstract: We present the first results of neutral carbon ([C I] at 492 GHz) and carbon monoxide (CO) mapping of the Vela Molecular Ridge cloud C and G333 giant molecular cloud complexes with the NANTEN2 and Mopra telescopes. For the mapped regions so far, we found that [C I] has very similar emission profiles to 13CO with comparable line widths. [C I] has opacity of 0.1 - 1.3, the [C I]/13CO peak brightness temperature ratio is between 0.2 to 0.8 across the mapped regions. [C I] column density is an order of magnitude lower than that of 13CO. H2 column density derived from C I is comparable to values obtained from 12CO. Our data show C I is mainly found among gas with low temperatures (below 20 K), this possibly explains the comparable H2 column density that both [C I] and 12CO under estimate column density, as the C I in the warmer gas is in a higher energy state ([C I] at 810 GHz), and thus it is likely that observations of both [C I] transitions are needed to recover the total H2 column density.