Scientific Justification:
Molecular lines can be detected in absorption
in the spectrum of a background compact source. Observing molecules in
absorption is extremely powerful: the detection sensitivity is not
dependent on the properties of the system under study but rather
depends solely on the a priori unrelated characteristics of the
background sources. Absorption line systems provide the most detailed
information on the dense, pre-star forming Inter-Stellar Medium (ISM)
in galaxies at cosmologically significant redshifts as well as the
global cosmic chemical evolution. In particular, molecular gas is
known to measure mass better than optical light. These lines are
expected to be very narrow at sub-mm wavelengths. Today, only a
handful of molecular detections are known in absorption. Only few
successful observations have been possible despite many hours of
dedicated observations: 4 detections of CO in absorption have been
reported (Drinkwater et al. 1996, AA, 312, 771; Wiklind & Combes 1994,
AA, 288L, 41; Combes & Wiklind 1995, AA, 303L, 61; Wiklind et
al. 1995, AA, 297, 643; Curran et al. 2004, MNRAS, 352, 563). Among
these 4 detections, two are found to be associated with the background
source. Therefore, we know so far of only two genuine CO detections
in intervening absorbers: 1) the z(abs)=0.685 system towards
z(em)=0.936 BLac B0218+357 (Wiklind & Combes, 1995, A&A, 299, 382) and
2) the z(abs)=0.886 system towards z(em)=2.507 PKS 1830-211 (the same
quasar has another z(abs)=0.192 double system along its line-of-sight;
(Wiklind & Combes, 1996, Nature, 379, 139).
Technical Justification: Here, we propose to search for molecular
absorption line systems in front of a known strong flat spectrum radio
source, PKS 1830-211. From 30--IRAM and 15--SEST observations, many
molecules have already been observed in this absorber, including HCO,
HCN, O2 etc. We propose here to observe o-H2O, HCl(1<-0) and o-NH3 in
this system. We choose to observe these low-excitation lines because
the higher J levels of CO were not detected in previous short science
verification observations, indicating that the excitation temperature
is low. Note that H2O towards the other molecule rich absorber
B0218+357 has already been detected, illustrating the feasability of
our proposed observations (Combes & Wiklind, 1997, ApJ, 486L, 79).
The rest frequencies of the transitions we propose to observe are
556.936 GHz, 624.975 GHz and 572.498 GHz respectively (Schoier,
F.L. et al. 2005, AA, 432, 369). These correspond to the following
redshifted frequencies: 295.328 GHz, 331.408 GHz and 303.580 GHz. The
bandwidth of 1024 MHz with 2048 channels would give a velocity
resolution of 0.5 km/s. Other molecular lines in this system show
velocity widths of ~ 30 km/s, implying that we can rebin the spectrum
to increase the signal to noise, and still resolve the absorption
profile. The quasar is known to be 0.5 Jy at these
frequencies. Typical system temperatures in the 2A band are 200K,
which means we will reach noise levels of ~ 3.5 mK per channel per
session of 2 hours on and 2 hours off. The noise levels that we expect
are very similar to those from Combes & Wiklind (1997, ApJ, 486L, 79)
from their IRAM observations of the absorber against B0218+357. The
flux of our background source is also comparable to that of B0218+357,
which means that we will reach similar optical depth limits in PKS
1830-211. Combes & Wiklind detected the H2O line at 5 sigma.
The rms noise level in our observations is ~3.5 mK per 0.5 MHz
channel, but given the expected width of the line, we can rebin the
spectrum to at least 5 MHz, giving an rms noise level of 1.1 mK. The
H2O line detected by Combes & Wiklind (1997, ApJ, 486L, 79) had a
peak depth of 5.5 mK. We therefore estimate that 4 hrs per absorption
line are needed (i.e. including position switching). In the period 19-29
October 2005, this target is expected to be visible in the early hours
of the night.